The comeback of the Labtour[2024]

  • Context : In line with our previous initiatives during autumn 2022/winter 2023,  we are continuing to strengthen community interaction within KiNOA by organizing laboratory visits.
  • Deadline for enlisting the visits : 15/03/2024
  • Where ? on the framalink sent the 28/02
  • Remind : The concept is to welcome colleagues to your lab (or experiment) at a time and duration that suits your schedule.
  • Encourage you to share this information with all members of your group. It presents a valuable opportunity for them to broaden their understanding of chirality.

GPR LIGHT Symposium 2024 (Tuesday 21st May 2024)

  • When ? Tuesday 21st May 2024
  • Where ? Institut d’Optique d’Aquitaine
  • Why ? Come and attend the 2nd symposium of the LIGHT Major Research Programme (GPR LIGHT)! Presentation of the activities of the GPR with the communities concerned, meeting of the academic and industrial partners of the LIGHT Initiative, discussions on future projects.
  • ** Registration Free but Mandatory >> https://framaforms.org/gpr-light-symposium-2024-21st-may-1708076187

Bulk electrosynthesis of patchy particles with highly controlled asymmetric features

2024-01-16
News: Asymmetric modification of particles with various patches of different composition and size at predefined positions is an important challenge in contemporary surface chemistry, as such particles have numerous potential applications, ranging from materials science and (photo)catalysis to self-assembly and drug delivery. However, approaches allowing the synthesis of this kind of complex objects in the bulk of a solution in a straightforward way are currently lacking. In this context, bipolar electrochemistry (BE) is a powerful technique for the asymmetric modification of conducting objects. Herein, this approach is used for the highly controlled modification of particles with different metal patches, generated at specific locations of isotropic objects. The synthesis is carried out in the bulk of the solution and leads to predefined patterns of increasing complexity, including even a specific chiral arrangement of the patches.
Laboratory : ISM

Modulation of circularly polarized luminescence by swelling of microgels functionalized with enantiopure [Ru(bpy)3]2+ luminophores

2023-12-20
News: Chemoresponsive microgels functionalized with enantiomeric D- or K-[Ru(bpy)3] 2+ showed tunable chiroptical properties upon swelling and shrinking. The tuning is triggered by a modulation of the local mobility of [Ru(bpy)3]2+ upon addition of fructose, controlling inter- actions and distances between [Ru(bpy)3]2+ and phenylboronic acid. DOI: 10.1039/D3CC04391F
Laboratory : CBMN/ISM/Univ. Genève/Kumamoto Univ/Tohoku Univ.

Chirality Related Properties in Helicene and Tetrathiafulvalene based Materials

2023-12-22
News: Who ? Dr. Narcis AVARVARI du Laboratoire MOLTECH Anjou  (Université d'Angers).
Where ? salle de conférences de l'ISM (3e étage)
When ? 22 dec. 2023, 10h30-11h30
Keywords: CISS effect, eMChA effect, Helicene, Conductivity, TTF
Abstract and references on  : https://www.ism.u-bordeaux.fr/actualites/dr-narcis-avarvari
Laboratory : ISM

Deadline sur PEPR LUMA

2023-09-15
News: Le PEPR LUMA invite les chercheurs travaillant dans les axes de recherche sur la chiralité listés sur : https://www.pepr-luma.fr/axes/chiralite/ de déposer des lettres d'intention (<3 pages) avant le 15 sept. 2023 afin de construire lors de workshops en visioconférence (dates prévisionnelles 27-28 sept. 2023) des consortia (typiquement 10 équipe de recherche travaillant ensemble) qui répondront aux AMI-appel à manifestation d'intérêts- auprès de l'ANR-PEPR-LUMA en automne 2023. Le template de la lettre d'intention et les dates clefs sont consultables sur : https://www.pepr-luma.fr/appels/appel-a-manifestations-dinteret-recherche-thematique/ NB : les AMI sont des financements sur 5 ans n'incluant pas de l'équipement >50 keuros.
Laboratory : chiralité

Design, preparation and chiroptical characterization of chiral molecules and monolayers for Chirality Induced Spin Selectivity studies

Supervisor : mathieu.gonidec@icmcb.cnrs.fr
Laboratory/campus : ICMCB
Starting date : 2023-09-15
Duration/month : 36
Preferred Majors for applicants : chemistry
The main goal of this project is to provide systematic comparative studies to rationalize the occurrence and magnitude of the CISS effect in molecular nanodevices. In order to reach those objectives, we will synthesize series of coordination compounds designed to present a range of stable chiroptical activities, that will be deposited as thin films or grafted as monolayers on metallic substrates while preserving both their structure and their enantiopurity. We will then thoroughly study the chiroptical properties of these thin films by a range of surface sensitive spectroscopies. Ultimately, the CISS effect induced by these chiral surfaces will be studied (partly in house, partly with the help of external collaborators) by integrating them into vertical charge transport devices to probe their spin dependent properties and analyze their CISS activity.

A correlated view of chiral-induced spin selectivity

Prof. Jonas Fransson (University of Uppsala)

Thursday May 4, 10 am

ICMCB amphitheatre – Conference de Quantum Matter

Lien vers les infos : QMBx seminar Jonas Fransson 2023 – Quantum Matter Bordeaux (cnrs.fr)

Chiral-induced spin selectivity is an intriguing phenomenon that, to our knowledge, rests on a foundation of structural chirality, spin-orbit interactions, and strongly non-equilibrium conditions. The effect is a measure of the response to changes in the magnetic environment coupled to the active region, and the phenomenology refers back to the experimental observations of substantial changes in the charge current amplitude through chiral molecules upon changes in the external magnetic conditions. Chiral-induced spin selectivity has been shown to not be limited to multistranded helical structures, such as double-stranded DNA molecules and bacteriorhodopsin, but has also been observed in, for example, various types of peptides and polyalanines and, recently, also in helicene.

In order to depart from the generic single electron, or, non-interacting models that have, quite unsuccessfully, been used in attempts to describe the chiral-induced spin selectivity effect, it is proposes to include many-body effects, arising from, e.g., electron-electron or electron-vibron interactions. In cooperation with spin-orbit interactions, the many-body interactions generate exchange splitting between the spin channels which is viable for the chiral-induced spin selectivity phenomenon. By constructing models comprising either electron-electron or electron-vibron interactions, it can be demonstrated that the chiral-induced spin selectivity effect increases by several orders of magnitude compared to the results from any non-interacting description. The phenomenology of the chiral-induced spin selectivity effect indicates that charge transfer within the chiral molecule is accompanied by the emergence of intra-molecular spin-polarization.

  1. Fransson, Chirality induced spin-selectivity: The role of electron correlation: J Phys Chem Lett, 10, 7126 (2019).
  2. Fransson, Vibrational origin of exchange splitting and chiral-induced spin selectivity: Phys Rev B, 102, 235416 (2020).
  3. Fransson, Charge Redistribution and Spin Polarization Driven by Correlation Induced Electron Exchange in Chiral Molecules: Nano Lett, 21, 3026 (2021).
  4. Fransson, Charge and Spin Dynamics and Enantioselectivity in Chiral Molecules: J Phys Chem Lett, 13, 808 (2022).

Contact: Elizabeth Hillard <elizabeth.hillard@icmcb.cnrs.fr>